introduction of brönsted acidic ionic liquid supported on nanoporous na+-montmorillonite as an efficient catalyst for the synthesis of 2-amino-tetrahydro-4h-pyrans
نویسندگان
چکیده
nanoporous sodium montmorillonite clay (na+-mmt) was used as a support for the immobilization of 1-methyl-3-(trimethoxysilylpropyl)-imidazolium hydrogen sulfate (na+-mmt-[pmim]hso4). this catalyst showed excellent catalytic activity for the preparation of 2-amino-3-cyano-5-oxo-5,6,7,8-tetrahydro-4h-benzopyrans via three-component reactions between aldehydes, dimedone and malononitrile. the procedure gave the products in high yields within short reaction times. also, this catalyst can be reused at least for five times without loss of its catalytic activity. all the products were characterized using melting point, ir, 1h nmr and 13c nmr and were identified by comparison of their spectra with those of authentic samples.
منابع مشابه
Introduction of Brönsted acidic ionic liquid supported on nanoporous Na+-montmorillonite as an efficient catalyst for the synthesis of 2-amino-tetrahydro-4H-pyrans
Nanoporous sodium montmorillonite clay (Na+-MMT) was used as a support for the immobilization of 1-methyl-3-(trimethoxysilylpropyl)-imidazolium hydrogen sulfate (Na+-MMT-[pmim]HSO4). This catalyst showed excellent catalytic activity for the preparation of 2-amino-3-cyano-5-oxo-5,6,7,8-tetrahydro-4H-benzopyrans via three-component reactions betw...
متن کاملIntroduction of Brönsted acidic ionic liquid supported on nanoporous Na+-montmorillonite as an efficient catalyst for the synthesis of 2-amino-tetrahydro-4H-pyrans
Nanoporous sodium montmorillonite clay (Na+-MMT) was used as a support for the immobilization of 1-methyl-3-(trimethoxysilylpropyl)-imidazolium hydrogen sulfate (Na+-MMT-[pmim]HSO4). This catalyst showed excellent catalytic activity for the preparation of 2-amino-3-cyano-5-oxo-5,6,7,8-tetrahydro-4H-benzopyrans via three-component reactions betw...
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چکیده ندارد.
Li(OHCH2CH2NH2)(CF3OAC): A novel and homogeneous acidic ionic liquid catalyst for efficient synthesis of 2-amino-4H-chromene derivatives
The ionic liquid Li(OHCH2CH2NH2)(CF3OAC) was found to efficiently catalyze the three-component reaction between different enols, aldehydes, and malononitrile , leading to rapid synthesis of 2-amino-4H-chromene derivatives in fairly high yields. The catalyst is easily prepared, highly stable, simple to handle and recycled for several times without significant loss of activity. The method is simp...
متن کاملLi(OHCH2CH2NH2)(CF3OAC): A novel and homogeneous acidic ionic liquid catalyst for efficient synthesis of 2-amino-4H-chromene derivatives
The ionic liquid Li(OHCH2CH2NH2)(CF3OAC) was found to efficiently catalyze the three-component reaction between different enols, aldehydes, and malononitrile , leading to rapid synthesis of 2-amino-4H-chromene derivatives in fairly high yields. The catalyst is easily prepared, highly stable, simple to handle and recycled for several times without significant loss of activity. The method is simp...
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Aromatic aldehydes are efficiently condensed with 2'-hydroxyacetophenone by polymer-supported basic ionic liquid as an excellent heterogeneous catalyst utilizing the Claisen–Schmidt reaction. Microwave irradiation has been employed, providing flavanone in good yield and short reaction time.
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عنوان ژورنال:
iranian journal of catalysisجلد ۷، شماره ۱، صفحات ۲۱-۲۶
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